{(1R,2R)-N,N′-Bis[2-(N-methylanilino)benzylidene]cyclohexane-1,2-diamine-κ2 N,N′}dichloridoiron(II)
نویسندگان
چکیده
In the title compound, [FeCl(2)(C(34)H(36)N(4))], the Fe(II) ion is coordinated by two Cl atoms and by two N atoms from a (1R,2R)-N,N'-bis[2-(N-methyl-anilino)benzyl-idene]cyclo-hexane-1,2-diamine ligand in a distorted tetra-hedral geometry. The mol-ecule has approximate C(2) point symmetry. The dihedral angles between the phenyl and benzene rings on either side of the ligand are 64.56 (14) and 65.61 (13)°.
منابع مشابه
(1R,2R,E,E)-N,N′-Bis(4-chlorobenzylidene)cyclohexane-1,2-diamine
The title Schiff base ligand, C(20)H(20)Cl(2)N(2), was prepared by condensation of commercially available p-chloro-benzalde-hyde and (R,R)-1,2-diammonium-cyclo-hexane mono-(+)-tartrate. The cyclo-hexane ring adopts a chair conformation. The dihedral angle between the two aromatic rings is 62.52 (8)°. The crystal structure is stabilized by an inter-molecular C-H⋯Cl hydrogen bond.
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In the title compound, [HgCl(2)(C(12)H(19)N(3))], the Hg(II) ion is coordinated by three N atoms of the (1R,2R)-N-(pyridin-2-ylmeth-yl)cyclo-hexane-1,2-diamine ligand and by a Cl atom in the basal plane, and by a second Cl atom in the apical position, within a distorted square-pyramidal geometry. The coordination of the enanti-opure ligand to the metal atom renders the central N atom chiral wit...
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متن کاملcis-[1,4-Bis(diphenylphosphanyl)butane-κ2 P,P′]dichlorido(cyclohexane-1,2-diamine-κ2 N,N′)ruthenium(II) dichloromethane monosolvate
In the title compound, [RuCl(2)(C(6)H(14)N(2))(C(28)H(28)P(2))]·CH(2)Cl(2), the Ru(II) ion is coordinated in a slightly distorted octa-hedral environment, formed by two cis-oriented chloride ligands, two cis P atoms of a 1,4-bis-(diphenyl-phosphan-yl)butane ligand and two cis-chelating N atoms of a bidentate cyclo-hexane-1,2-diamine ligand. In the crystal, pairs of mol-ecules form inversion dim...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012